CH3COOH is a weak acid and HBr is strong acid. Let us see the reaction of HBr + CH3COOH.
CH3COOH naturally occurs by excretion from certain bacteria and HBr is a inorganic compound, soluble in water, colorless gas.
This article will discuss some facts about CH3COOH and HBr reaction, like net ionic equation, conjugated pair etc.
What is the product of HBr and CH3COOH
Acetic aldehyde (CH3CHO) , dibromine (Br2) and water (H2O) are the products of HBr+CH3COOH reaction.
CH3COOH + HBr = CH3CHO + Br2 + H2O
What type of reaction is HBr and CH3COOH
CH3COOH + HBr is a endothermic as well as elimination reaction.
How to balance HBr +CH3COOH
The reaction CH3COOH + HBr is balanced using the following steps :
CH3COOH +HBr = CH3CHO +Br2 +H2O
- Firstly we count the number of atoms on the reactants and product sides.
- If the number of reactant atoms and product atoms are not same then we have to multiply smallest figure according to formula.
- In the above equation, number of H atom and Br atom are not same.
- So,we should multiply HBr by 2.
- Thus the balance equation according to the above points is
- CH3COOH + 2HBr = CH3CHO + Br2 +H2O
HBr + CH3COOH titration
Titration is not possible in the HBr +CH3COOH reaction because strong acid HBr ionize while weak acid CH3COOH does not ionize.
HBr + CH3COOH net ionic equation
The net ionic equation for HBr +CH3COOH is-
CH3COO–(Aq) + 2HBr(l) + H3O+(Aq) = CH3CHO(l) + Br2(g) + 2H2O(l)
Follow the steps mentioned below to get net ionic equation.
- CH3COOH is a weak acid, so it cannot dissociate completely at a time. It dissociates partially in an aqueous solution.
- The dissociation of acetate ions is not the spectator ions.
- CH3COOH + H2O = CH3COO– + H3O+
- HBr is a strong acid, so it dissociates completely.
- 2HBr = 2H+ + 2Br–
- If we combine equation 1 and 2, we can get below equation
- CH3COOH + H2O + 2HBr = CH3COO– + H3O+ + 2H+ + 2Br–
- Thus the net ionic equation for the HBr and CH3COOH reaction is
- CH3COO– + H3O+ + 2HBr = CH3CHO + Br2 +2H2O
HBr + CH3COOH conjugate pairs
The conjugate pairs of the reaction HBr+CH3COOH are as mentioned below-
- Conjugate base of HBr is Br– and HBr conjugate acid is H3O+.
- Conjugate base of CH3COOH is acetate ion CH3COO– .
HBr and CH3COOH intermolecular forces
HBr + CH3COOH has the following intermolecular forces-
- Dipole – dipole interaction, dispersion forces and hydrogen bonding are present as intermolecular forces in CH3COOH.
- Dipole – dipole forces are present as intermolecular forces in HBr.
HBr + CH3COOH reaction enthalpy
For HBr +CH3COOH the reaction enthalpy value is 210.6 kJ /mol. It is calculated using the values given in the table below.
Compounds | Enthalpy of formation in KJ/mol |
---|---|
HBr | -119.6 |
CH3COOH | -491 |
CH3CHO | 52 |
Br2 | 0 |
H2O | -285.8 |
- Reaction enthalpy = (sum of reaction enthalpy of product) – (sum of reaction enthalpy of reactants)
- Reaction enthalpy = [52 + ( – 285.2 ×2)] – [-(2×119.6)- 491] KJ/mol
- Reaction enthalpy = 210.6 KJ/mol
Is HBr + CH3COOH a buffer solution
HBr + CH3COOH is not a buffer solution because HBr is a strong acid and CH3COOH is a weak acid with pH values 0.21 and 2.4 simultaneously.
Is HBr + CH3COOH a complete reaction
HBr + CH3COOH is a complete reaction because it gives CH3CHO, Br2, H2O as products.
Is HBr + CH3COOH an exothermic or endothermic reaction
HBr + CH3COOH is an endothermic reaction because CH3COOH being a weak acid does react with HBr, so external energy is required to break the bond.
Is HBr + CH3COOH a redox reaction
HBr +CH3COOH is a redox reaction because oxidation state of reactants and products are changed as shown below.
CH3COO-1(aq) + H3O+1(aq) + 2HBr-1(l) = CH3CHO-2(l) + Br2(g) + 2H2+2O-2(l)
Is HBr + CH3COOH a precipitation reaction
HBr + CH3COOH is not a precipitation reaction because it does not form precipitate. Reactants and products CH3CHO (acetaldehyde) , Br2 (dibromine) are miscible in water.
Is HBr + CH3COOH reversible or irreversible reaction
HBr + CH3COOH is a reversible reaction because the product CH3CHO, Br2, H2O of the reaction does not remain as residue.
Is HBr + CH3COOH displacement reaction
HBr +CH3COOH is not a displacement reaction because addition of 2 Bromine atoms takes place from 2 molecules of HBr to form Br2 as a product and elimination of H+ ion from CH3COOH took place to form acetate ion in aqueous solution and gives CH3CHO.
Conclusion
HBr is a strong acid in comparison to CH3COOH because of these facts reaction of HBr and CH3COOH takes place as redox reaction, reversible reaction and complete reaction.
Hii.. I am Soumya Tiwari. I have completed my graduation in pharmaceutical chemistry and currently pursuing Masters degree in chemistry. I have participated in several government programmes like India International Science Festival. Lets connect through LinkedIn